A Study of the Process of Removing Liquid Organic Substance from Textile Material by Powder and the Substantiation of the Laws of Its Flow
https://doi.org/10.35825/2587-5728-2023-7-4-319-337
Abstract
The relevance of this research is determined by the scientific contradiction between the need to increase the efficiency of degassing powder formulations when processing textile materials contaminated with drops of toxic chemicals, and the lack of such an opportunity, since the application of modern theories of degassing is difficult here due to the lack of knowledge about the diffusion stage that determines the transition of liquid from tissue into powder. The purpose of this article is to study the process of removing a liquid organic substance from a textile material by powder, on which it is applied discretely in the form of small drops, and the laws according to which this process flows. Materials and methods. To substantiate the experiments, publications available through the databases Scopus, eLIBRARY, SRussian National Public Library for Science and Technology, Federal Institute of Industrial Property, Google Scholar, etc. were studied. When carrying out the experiments, the relevant methods of microphotography, mass measurement, separation of powder into different fractions, measurement of the diameter of powder particles and fabric fibers, and statistical processing of experimental data were used. The discussion of the results. A technique has been developed that makes it possible to experimentally study the process of removing liquid organic matter from textile material by powder. As a result of the research, the process of removing a liquid organic substance from a textile material by powder, onto which it is applied discretely in the form of small drops, was studied for the first time. Based on theoretical studies and experimental data, several laws (regularities) for the removal of the liquid phase of organic matter from textile material and the requirements for rate constants for the removal of the liquid phase of organic matter from textile material using powder formulations were substantiated for the first time to ensure the required completeness of the decontamination of combat equipment of military personnel contaminated with toxic chemicals. The conclusion. 1) the proportion of the removed liquid phase of organic matter from a textile material is directly proportional to the rate constant for the removal of the liquid phase of organic matter by powder, which takes into account only the processing time of the powder formulation, and the square root of the processing time of the powder formulation («capillary law of removal of liquid organic matter from textile material by powder»); 2) when changing the exposure to contamination and the time of powder treatment, it is formulated as follows: «The proportion of the removed liquid phase of organic matter from a textile material is directly proportional to the rate constant for the removal of the liquid phase of organic matter by the powder, taking into account the time of treatment with the powder formulation and the exposure to contamination, and the square root of the time of treatment with the powder formulation, and is also inversely proportional to the square root of the time of contamination.»
Keywords
About the Author
P. N. KolesnikovRussian Federation
Pavel N. Kolesnikov - Senior researcher at the scientific research laboratory for the assessment of physiologically active substances. Cand. Sci. (Chem.)
Gorky Street 16, Kostroma 156013
References
1. Novikov AM, Novikov DA. Methodology. M.: Sinteg; 2007. 668 p. ISBN 978-5-89638-100-6. EDN:pfgvjn (in Russian).
2. Novikov AM, Novikov DA. Methodology of scientific research. M.: Librokom, 2013. 270 p. ISBN 978-5-397-03714-3. EDN:xqhhqw (in Russian).
3. Novikov AM, Novikov DA. Methodology: Dictionary of the system of basic concepts. M.: Librokom; 2013. 208 p. ISBN 978-5-397-03756-3. EDN:ztgkbd (in Russian).
4. Novikov DA. Laws, laws and principles of management. Innovations in Management. 2016;1(7);44–53 (in Russian).
5. Dyachenko AN, Shagalov VV. Chemical kinetics of heterogeneous processes: tutorial. Tomsk: National Research Tomsk Polytechnic University, 2014. 99 p. EDN:vwwqnz (in Russian).
6. Stepanovskikh EI, Alekseeva TA, Brusnitsyna LA. Determination of the properties of heterogeneous and homogeneous systems. Yekaterinburg: Ural Federal University named after the first President of Russia B.N. Yeltsin, 2022. 143 p. ISBN 978-5-7996-3420-9. EDN:gbexfn (in Russian).
7. Kolesnikov PN, Khantov VP, Migachev YuS, Sosnin NI. Polydisperse powder formulation with nanoparticles for degassing of textile materials. Science and military security. 2016; (7):101–4. EDN:xxbglz (in Russian).
8. Karpov VP, Kazimirov OV, Kapkanets KS. Scientific and Technical Analysis of the Main Trends in Research during the Development of New Decontaminants and Decontaminating Equipment. Journal of NBC Protection Corps. 2017;1(1): 42–52. EDN:yoiibv (in Russian).
9. Mkhitaryan VS, Shishov VF, Kozlov AYu. Analysis of data in MS EXEL. Textbook. Moscow: INFRA-M; 2021. 320 p. https://doi.org/10.12737/2842. ISBN 978-5-16-004579-5 (in Russian).
10. Gatedyuk OV, Manyukova NV. Workshop on probability theory and mathematical statistics. textbook. St. Petersburg: Publishing House «Lan»; 2022. 132 p. ISBN 978-5-8114-9842-0 (in Russian).
11. Muntyan ER, Balabaeva IYu, Yelchanova NB. Laboratory workshop on the course on the basis of information and communication technologies: educational and methodological manual. Rostov-on-Don Taganrog: Publishing house Southern Federal University (Rostov-on-Don); 2022. 180 p. (in Russian).
12. Gmurman VE. Probability theory and mathematical statistics: a textbook for secondary vocational education. 12th ed. Moscow: Yurite Publishiftg House; 2020. 479 p. ISBN 978-5 534-00859-3 (in Russian).
13. Kosheleva MK, Golykh RN, Novikova TA. Experimental study of kinetics of tissue drying process using ultrasonic field for energy saving. Collection of scientific works of the International Scientific and Technical Symposium «Improving Energy Efficiency and Environmental Safety of Processes and Apparatuses of Chemical and Related Industries», dedicated to the 110th anniversary of A.N. Planovsky (ISTS «EESTE-2021»): V. 2. M.: FSBEI HE «RSU named after A.N. Kosygin»; 2021. Р. 46–9. ISBN 978-5-00181-166-4 (in Russian).
14. Zheltov AYa, Perevalov VP. Chemistry and organic dye technology. Color of compounds. Textbook for bachelor's and master's degree 2nd ed., Rev. and additional. M.: Publishing House Yuryt; 2017. 347 р. ISBN 978-5-534-05067-7 (in Russian).
15. Peisakhovich AA, Pavutnitsky VV. Vapor-phase method of dyeing synthetic sewing threads and yarns. Textile industry magazine. 2010;(4):34–6. EDN:mvszxz (in Russian).
16. Mcgarvey DJ, Creasy WR, Morrissey КМ, Hendrickson DM, Durst HD. А Decontamination system for chemical weapons agents using a liquid solution on a solid sorbent Israel Institute for Biological Research, PO Box 19, Ness-Ziona, Israel R and T Directorate, Edgewood Chemical and Biological Center (EСВС), Aberdeen Proving GroundEdgewood Area, United States SAIC, Gunpowder Branch, P.O. Box 68, Aberdeen Proving Ground, MD 21010, United States, 2009. P. 1114–21. https://doi.org/10.1016/j.jhazmat.2008.04.083
17. Volkov VA, Ageev AA. Kinetic method for determining the capillary properties of textile materials. Sciences of Europe. 2016;(6-2(6)):15–9. EDN:xljpgf (in Russian).
18. Shustov YuS, Kiryukhin SM, Davydov AF, Bulanov YaI, Gorshkova SS. Textile material science. Laboratory workshop. Ed. 4th, revised and additional: Limited Liability Company «Scientific and Publishing Center INFRA-M», 2021. 357 p. ISBN 978-5-16-016514-1. https://doi.org/10.12737/1172012. EDN:ggtmnc (in Russian).
19. Petrova LV, Khusnutdinova RR, Babitskaya KI. Physical basics of underground hydromechanics. Tutorial. Ufa: Publishing House of UGNTU; 2021. 123 р. (in Russian).
20. Zaitsev AN, Ismailov ShN. Technologies for the localization and elimination of sources of chemical contamination in accidents with releases of emergency chemically hazardous substances in emergencies of various types. Safety problems in emergency response. 2015;(1-1(4)):220–4. EDN:vlcrun (in Russian).
21. Krivonos OK, Ilyushchenko AF, Petyushik EE, Borodeyko AI, Mikulich DA. Methods of measuring the wettability of the surface of particles of solid-phase components of energy-saturated heterogeneous composite material. New materials and technologies: powder metallurgy, composites, protective coatings, welding. Materials of the 14th International Scientific and Technical Conference dedicated to the 60th anniversary of powder metallurgy in Belarus, Minsk, September 09-11, 2020. Minsk: Republican unitary enterprise «Publishing House «Belarusian Science»; 2020. Р. 369–73. EDN:ZSMOSS. ISBN 978-985-08-2628-2. (in Russian).
22. Markitanova LI. Protection of the population in case of chemical infection. Educational and methodological manual. St. Petersburg: St. Petersburg National Research University of Information Technologies, Mechanics and Optics; 2015. 33 р. EDN:zuymdf (in Russian).
23. Antonov NS. Special treatment in the US Ground Forces. Foreign Military Review. 1990;(5):21–7 (in Russian).
24. Fitch JP, Raber Е, Imbro DR. Technology challenges in responding to biological or chemical attacks in the civilian sector. Science. 2003;302(5649):1350–4.
25. Tomas C, Krykorkova J. Study of Decomposition of Chemical Warfare Agents using Solid Decontamination Substances. Ministry of Interior–General Directorate of the Fire Rescue Service CR, Population Protection Institute, Czech Republic. Toxics. 2019;7(4):63. https://doi.org/10.3390/toxics7040063
26. Polovinkina ON, Kirillov NV, Mikhailenko VS. Special processing at the modern stage of development. Bulletin of MANEB. 2023;28(2):44–9. EDN:lvzabc (in Russian).
27. Tuorinsky SD, Lenhart MK. Medical aspects of Chemical Warfare. Washington: Walter Reed Army Medical Center; 2008. 843 р. ISBN 978-0-16-081532-4.
28. Timoshevsky AA, Sapozhnikov AV. Military toxicology, radiology and medical protection. Materials for selfpreparation for classes at the training camp in the discipline. Moscow: First Sechenov Moscow State Medical University of the Ministry of Health of the Russian Federation (Sechenov University); 2018. 89 р. EDN:izgmvs (in Russian).
29. Kolesnikov PN, Bakin AN, Ivanov AN, Sinkelev AP, Bolotov AM. Polydisperse powder formulation with nanoparticles for degassing of textile materials. Pat. 2585028 Russian Federation. Applicant and patent holder VARHBZ. dec. No. 2014150268/05 12/11/2014; publ. May 27, 2016, Bull. No. 15. EDN:wawclz (in Russian).
30. Kolesnikov PN, Khantov VP. Development of a powder formulation for the effective removal of toxic chemicals from textile material. Journal of NBC Protection Corps. 2017;1(4):41–9. EDN:yoqcfv (in Russian).
31. Kolesnikov PN, Kiselev AM. Organizational issues on the use of nanopowders to reduce the contamination of clothing materials and special protective equipment contaminated with liquid potent poisonous substances as a result of an accident at a chemically hazardous facility. State Reg: State Regulation of Public Relations. 2015;(1(11)):20. EDN:udllhr (in Russian).
32. Chefranov SG. Energetically optimal non-stationary flow modes of viscous uncompressible fluid. Izvestia of the Russian Academy of Sciences. Fluid and gas mechanics. 2017;(2):36–49. https://doi.org/10.7868/S0568528117020074. EDN:ykulut (in Russian).
33. Kolesnikov PN, Khantov VP, Migachev YuS, Gladin RA. Study of the removal of the toxic chemical simulant O-isobutyl-S-2-(N,N-diethylamino)-ethylmethylphosphonate from the surface of textile materials by powder formulations. Science and military security. 2017;(3(10)):72–7. EDN:ziavxh (in Russian).
34. Kolesnikov PN, Bakin AN, Ivanov AN, Sinkelev AP, Bolotov AM. Applicant and patent holder MA NBC Protection. Pat. 2585027 Russian Federation. Applicant and patent holder VARHBZ. dec. No. 2014150267/05 12/11/2014; publ. May 27, 2016, Bull. No. 15. EDN:qasyyh (in Russian).
35. Kolesnikov PN, Kiselev AM. Simulator of infection of textile materials with O-isobutyl-S-2-(N,Ndiethylamino) ethylmethylphosphonate and its removal by powder formulations. Bulletin of the Technological University. 2016;19(3):82–5. EDN:vntyxj (in Russian).
36. Kolesnikov PN, Ivanov AN. The use of nanopowders to reduce the risk of textile materials of clothing and special protective equipment contaminated with liquid potent poisonous substances as a result of an accident at a chemically hazardous facility. News of higher educational institutions. Technology of the textile industry. 2015;(5(358)):211–4. EDN:vaykiv (in Russian).
Review
For citations:
Kolesnikov P.N. A Study of the Process of Removing Liquid Organic Substance from Textile Material by Powder and the Substantiation of the Laws of Its Flow. Journal of NBC Protection Corps. 2023;7(4):319-337. (In Russ.) https://doi.org/10.35825/2587-5728-2023-7-4-319-337